9.226 133.047 l f )Tj f /TT0 1 Tf h /TT1 1 Tf W* n feet, dizziness, lightheadedness, chest pain, muscle pain or flushing. W* n 0000039457 00000 n h 604.312 428.8 l h 9.226 138.009 l 121.524 443.024 l ( )Tj ( )Tj )Tj EMC /TT1 1 Tf 0 -1.201 TD f 602.774 618.319 l 9.226 618.319 l )Tj 122.666 52.702 l 362.335 78.843 l 0000001412 00000 n ( R 35 Causes severe burns. 10.764 679.395 l )Tj h f 0 -1.2 TD /TT0 1 Tf EMC Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation: Symptoms of allergic. f q 0000000880 00000 n )Tj 600.467 684.507 l ( No data available. W* n 602.774 442.255 l 8.457 66.157 l 9.226 133.047 593.548 26.141 re (Inhalation:)Tj /TT1 1 Tf EMC 363.873 53.471 l 0 18 612 756 re 7.688 379.942 m 10.764 683.738 l h 10.764 764.141 m 602.774 701.717 l 0.753 0.753 0.753 rg 0 0 0 rg (pyridine, dimethyl formamide, acetic acid, acetic anhydride, acetone, di\ ethyl ether, ethanol, methanol, camphor, )Tj 0.313 0.313 0.313 rg q 363.104 79.612 m 0000066364 00000 n f 604.312 274.942 m f /Artifact <>BDC W* n (fighters immediately. f 9.226 227.648 593.548 26.141 re EMC 10.715 0 Td Q Q 0000002339 00000 n 376.641 442.255 l /TT0 1 Tf 377.41 443.024 m h 455.54 630.236 l 123.434 53.471 l ET f Cancer )Tj 0 -1.1 TD ( )Tj Avoid contact with clothing and other combustible materi\ als. 601.236 492.615 l (Appearance:)Tj 11.533 271.097 l 601.236 655.563 l W* n (OSHA:)Tj 600.467 493.384 l (https://fscimage.fishersci.com/msds/95984.htm \(5 of 6\)7/23/2007 11:01:\ 40 AM)Tj f /Artifact <>BDC (Boiling Point:)Tj /TT0 1 Tf )Tj /T1_1 1 Tf 8.457 429.569 l f q EMC 0 0 0 rg 305.231 542.588 l 8.457 93.067 m ( )Tj h f 157.229 617.55 m 9.226 247.263 593.548 26.141 re Exposur\ e may cause anemia and other blood )Tj 455.54 618.319 l 602.774 247.263 l h )Tj ( Known carcinogen )Tj ( 1 Reagent Lane )Tj ( )Tj 11.533 326.023 l Provide ventilation. Millions of kilograms are produced annually, mainly for … W* n W* n ( )Tj If victim is conscious and alert, give 2-4 cupf\ uls of milk or water. h ( immediately \(show the label where possible\). 9.226 80.381 l 363.104 93.067 m 601.236 495.668 l /TT0 1 Tf Q Prolonged or repeated ey\ e contact may cause conjunctivitis. (hazard - See 29 CFR )Tj 454.771 541.819 l /TT1 1 Tf 0 -1.201 TD /TT1 1 Tf (SARA Section 302 Extremely Hazardous Substances)Tj EMC ( )Tj 11.533 514.911 l f 0.753 0.753 0.753 rg h 484.526 443.024 l 0 18 612 756 re T* EMC 0 18 612 756 re 0000066279 00000 n 601.236 764.141 l T* (CHROMIUM TRIOXIDE, ANHYDROUS)Tj C\ ontact with other material may cause fire. f /WebCaptureBG BMC 600.467 725.551 l h Get medical aid immediately.\ )Tj 601.236 271.866 l h 0 -1.2 TD 7.688 700.179 l 601.236 764.141 m 8.457 429.569 m 363.104 66.157 l ( adverse effects in the aquatic environment. 0 -1.2 TD q 10.7638 0 0 10.7638 7.6884 104.9636 Tm 121.897 66.926 l 0.753 0.753 0.753 rg W* n h 602.774 159.187 l (the unborn child. 0000066099 00000 n (0.05 mg/m3 TWA \(as Cr\) \(listed )Tj h ( Solid )Tj 123.434 80.381 l f Possible risk of impaired fertility. 0 -1.1 TD 600.467 656.331 l 603.543 429.569 l /Artifact <>BDC 157.997 542.588 l 9.226 654.025 l 122.666 79.612 l /TT1 1 Tf 10.764 472.603 m ( )Tj Avoid generating dusty )Tj h q May require flooding )Tj EMC 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm 0000005309 00000 n 8.457 66.157 m /TT1 1 Tf 9.226 491.077 593.548 26.141 re h h Hexavalent chromium compounds (including chromium trioxide, chromic acids, chromates, chlorochromates) are toxic and carcinogenic. )Tj 602.774 677.857 l /TT0 1 Tf EMC 600.467 156.881 l q (Carcinogenicity:)Tj h /TT1 1 Tf 121.524 443.024 l 600.467 347.551 l h ( Facilities storing or utilizing this material should be equipped with a\ n eyewash facility and a )Tj 0.753 0.753 0.753 rg 9.995 0 0 9.995 432.3956 244.9805 Tm f /TT0 1 Tf (warranty of merchantability or any other warranty, express or implied, w\ ith respect to such information, and we assume no liabil)Tj 9.226 680.166 l 0 -1.201 TD 10.764 678.628 m ( )Tj 0.457 0.449 0.431 rg Q W* n 306.769 616.781 l 10.764 162.612 m 7.688 165.687 m 0 0 0 rg 377.41 443.024 l (Section 10 - Stability and Reactivity )Tj 600.467 347.551 l 8.457 456.479 m (rposes. 0000066012 00000 n h /TT1 1 Tf 34.553 0 Td 0 -1.201 TD 157.229 541.819 l h 11.533 135.353 l ( None of the chemicals in this material have an RQ. 0 18 612 756 re h %PDF-1.6 %âãÏÓ (ity resulting )Tj 9.226 381.48 l 0.313 0.313 0.313 rg 0 0 0 rg ( )Tj /TT1 1 Tf 70197 ( R 50/53 Very toxic to aquatic organisms, may cause long-term )Tj /TT0 1 Tf 8.457 93.067 m (Canada - DSL/NDSL)Tj 0 -1.201 TD 9.226 407.621 l 0 18 612 756 re h 363.873 78.843 l ( )Tj f h f 0 -1.1 TD 600.467 405.314 l 9.226 80.381 l 7.688 414.192 m 0 18 612 756 re Chromic acid (CrO 3 ), Chromic anhydride, Chromic oxide, Chromium(VI) oxide (1:3), Chromium trioxide, Zinc chromate CrO 3 : Dark-red, odorless flakes or powder. 9.226 497.206 l )Tj 604.312 457.248 l Q T* 0000066448 00000 n Poisoning by chromium is a prescribed disease in the UK and may entitle you to Industrial Industries Disablement Benefit. )Tj /TT1 1 Tf /TT1 1 Tf )Tj 363.873 105.753 l 604.312 738 l 0 -1.2 TD 10.764 140.022 m f EMC 604.312 379.942 l Q 0 -1.2 TD 122.666 106.521 m EMC 483.757 443.793 l h 7.688 498.743 m 601.236 134.584 l (https://fscimage.fishersci.com/msds/95984.htm)Tj /TT0 1 Tf Adverse reproductive effects have been re\ ported in animals. ( )Tj 120.755 442.255 l 8.2799 0 0 8.2799 7.6884 448.0562 Tm 454.771 631.005 m 123.434 66.926 l 0 0 0 rg 0.457 0.449 0.431 rg EMC 0000065882 00000 n /Artifact <>BDC /TT1 1 Tf 485.294 430.338 l h T* EMC f /T1_0 1 Tf May cause skin\ sensitization, an allergic reaction, )Tj Remove contaminated clothing and wash b\ efore reuse. 600.467 139.253 l f h (spray to keep fire-exposed containers cool. EMC EMC 603.543 66.157 m /TT1 1 Tf )Tj q 601.236 116.957 l Q ( )Tj 9.226 247.263 l 6.9196 0 0 6.9196 18 8.7488 Tm 9.226 349.857 l 604.312 541.05 l EMC The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. 10.764 683.738 m 604.312 709.878 m 602.774 253.789 l 604.312 541.05 l Q 0 -1.201 TD /TT1 1 Tf h If breathing is difficult, give oxygen. ( )Tj 9.226 701.717 l h f f /WebCaptureBG BMC )Tj 601.236 383.018 l /TT0 1 Tf T* q 9.226 616.781 l 0 -1.1 TD 600.467 656.331 l ( )Tj f 604.312 489.539 l 0 -1.1 TD )Tj 602.774 455.71 l EMC (https://fscimage.fishersci.com/msds/95984.htm)Tj (from its use. However, certain perovskite structured oxides are electronically conductive finding application in the cathode of solid oxide fuel cells and oxygen generation systems. ( )Tj 483.757 443.793 l 485.294 442.255 l f 120.755 442.255 l f )Tj X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? An increase in incidence of lung cancer has been f endstream endobj 35 0 obj<> endobj 36 0 obj<> endobj 37 0 obj<>stream 0000017597 00000 n 9.226 471.065 l /Artifact <>BDC uuid:1b58ec6f-7f68-47d2-aec3-496b1cf28cdb 10.764 706.803 m /TT1 1 Tf 602.774 654.025 l (Eyes:)Tj ET 0 0 0 rg /TT1 1 Tf 0 -1.2 TD /TT0 1 Tf ǍӳY�l��b��E���#S��sB�t��1��e]���6}�-�o�����=��ɼ��z��uQ�+f�`G:����QF���o��vp���L��a�_���~z�q��}��kR�=�������\����>��������^_/����� ����)�'TT��1zJ��R���E�,��/�xmC-��}�P;��?ƚ�¦�zQ�毟-�L����>;�:l�q`�/�ZI�g�� Pgd�! 604.312 681.703 m 9.226 105.753 l f 363.104 79.612 m (CHROMIUM TRIOXIDE, ANHYDROUS)Tj h (Chronic ingestion may cause effects similar to those of acute ingestion.\ May cause liver and kidney damage. (eyes. 7.688 245.725 l 604.312 226.111 l h 377.41 429.569 m 9.226 159.187 l 10.764 116.957 m 11.533 656.331 l h q 603.543 106.521 l /TT1 1 Tf 11.533 405.314 l f f 363.104 106.521 m 363.873 119.207 l /TT0 1 Tf /Artifact <>BDC 13.4548 0 0 13.4548 183.5145 748.1881 Tm EMC /Artifact <>BDC 7.688 467.183 l (l)Tj -4.499 -1.202 Td q W* n 0 -1.201 TD 603.543 119.976 l 602.774 497.206 l 602.774 93.836 l 602.774 323.717 l (A100-100, A100-212, A100-500, A98-212, A98-500, NC9210244, S79969ACS, XX\ A100100LB )Tj /TT0 1 Tf W* n f /TT1 1 Tf EMC 306.769 630.236 l (MSDS Name:)Tj 7.688 729.395 m Can react violently upon contact with reducing reagents, including organic matter, leading to ignition or explosion. 603.543 66.157 l (Section 313)Tj f EMC 600.467 410.348 l 0 -1.201 TD 484.526 443.024 l 0.929 -1.2 Td EMC /TT0 1 Tf ET 0 -1.201 TD f W* n W* n 602.774 93.836 l )Tj 454.003 630.236 l 26.509 0 Td BT 0 18 612 756 re 10.764 157.65 m h Hygroscopic: absorbs mo\ isture or water from )Tj )Tj h <]>> h 0000000663 00000 n /TT0 1 Tf q 0 -1.201 TD 0.313 0.313 0.313 rg 11.533 388.82 l f 8.457 52.702 l ( 3.4 )Tj (This product has been classified in accordance with the hazard criteria \ of the Controlled Products Regulations and the )Tj 0 -1.2 TD Q 7.688 51.934 l 9.226 654.025 593.548 26.141 re T* 604.312 245.725 l 377.41 443.024 m EMC f 363.104 93.067 m 0 0 1 rg 122.666 93.067 m )Tj 157.229 617.55 m sol.\) )Tj 604.312 705.536 l 9.9358 0 0 9.9358 7.6884 458.9516 Tm /TT0 1 Tf ( Follow the OSHA respirator regulations found in 29 CFR 1910.134 or Euro\ pean Standard EN 149. h /Artifact <>BDC 0 18 612 756 re 0 -1.201 TD /WebCaptureFN <>BDC EMC )Tj If you have any worries or problems about working with chromium or its compounds, ask your supervisor or safety representative to discuss them with your employer, or discuss them with the occupational health professional. 603.543 79.612 l (pH:)Tj 363.104 106.521 l (Section 1 - Chemical Product and Company Identification)Tj 11.533 140.316 l f 0.753 0.753 0.753 rg 0.457 0.449 0.431 rg ( s waste. 601.236 140.022 m f 601.236 139.547 l 0 -1.201 TD 0 0 0 rg f (Ingestion:)Tj h EMC 9.9358 0 0 9.9358 7.6884 94.8857 Tm 602.774 105.753 l 0 18 612 756 re 602.774 517.218 l 0.457 0.449 0.431 rg 9.226 494.862 l Chromium 6 compounds may also cause cancers of the nose and nasal sinuses. W* n ET /Artifact <>BDC f Q /TT0 1 Tf 0 -1.2 TD /TT1 1 Tf (which becomes evident upon re-exposure to this material. /TT0 1 Tf 11.533 725.551 l 0 -1.201 TD Q 156.46 616.781 l q /TT0 1 Tf f EMC /T1_0 1 Tf 602.774 471.065 l 9.226 497.206 l /Artifact <>BDC h )Tj 10.764 406.083 m (respiratory tract. /TT0 1 Tf 0 18 612 756 re 120.755 443.793 l /TT1 1 Tf 604.312 409.158 m ( R 26 Very toxic by inhalation. (Section 7 - Handling and Storage )Tj 602.774 133.047 l EMC /TT0 1 Tf h EMC Separate from combustible materials, halogens, sulf\ ides, metals. 376.641 430.338 l BT Human TCLo: ROUTE: Inhalatio\ n: DOSE: 110ug/m3. 0 -1.099 TD /TT1 1 Tf 600.467 410.348 l f h /T1_0 1 Tf (Section 15 - Regulatory Information )Tj 11.533 494.899 l 604.312 160.725 l Use with )Tj 0 -1.199 TD 306 631.005 m (Chromium\(VI\) oxide)Tj /Artifact <>BDC ( )Tj q 0000001388 00000 n 604.312 414.192 m (Ecotoxicity:)Tj 601.236 116.957 l W* n 454.003 618.319 l EMC /TT0 1 Tf h h 9.9358 0 0 9.9358 7.6884 360.9467 Tm 10.764 655.563 l /TT1 1 Tf 2007-07-23T11:01:40-04:00 /T1_0 1 Tf h 9.226 708.341 l 0 18 612 756 re /Artifact <>BDC 363.873 80.381 l f f 0 -1.2 TD Prolonged exposure to )Tj h (California Prop 65)Tj 0 -1.2 TD (Vapor Density:)Tj 0 0 0 rg 0 -1.2 TD 602.774 766.312 l 11.533 725.551 l 157.997 618.319 147.234 11.917 re 0.753 0.753 0.753 rg 604.312 51.934 l ( )Tj 0 18 612 756 re (1910.1026\) \(listed under )Tj /TT0 1 Tf 600.467 140.316 l (Chromium \(VI\) compounds\). (Odor:)Tj 10.764 248.801 l 0 18 612 756 re ( )Tj 601.236 134.584 l 362.335 53.471 l Q h 9.226 542.588 l ( Group 1 carcinogen)Tj f )Tj 9.226 381.48 l May cause allergic skin reaction. f (Potential Health Effects)Tj (Not available. (UN Number:)Tj f ( )Tj 0 -1.2 TD 8.457 456.479 l 9.9358 0 0 9.9358 7.6884 758.6238 Tm ( )Tj W* n (Hazard Symbols:)Tj 603.543 541.819 l 0 -1.201 TD 8.457 617.55 m 363.873 107.29 238.901 11.917 re 601.236 726.32 m 600.467 249.57 l /TT0 1 Tf h 157.229 631.005 m 11.533 249.57 l 601.236 706.803 l 27.798 0 Td (CrO3 )Tj 601.236 472.603 l Use a )Tj /TT1 1 Tf f 0 -1.199 TD f 0 18 612 756 re T* 603.543 93.067 l 363.873 65.388 l /TT1 1 Tf 377.41 456.479 m Q f h 602.774 141.56 l ( None of the chemicals in this product are listed as Priority Pollut\ ants under the CWA. ( no )Tj 601.236 411.117 m 362.335 78.843 l reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and. 2007-07-23T11:01:38-04:00 h 0 18 612 756 re ( )Tj 378.179 442.255 l 16.205 4.2 Td /TT0 1 Tf 11.533 229.955 l # denotes a toxic chemical or chemicals subject to reporting requirements of Section 313 of Title Ill … EMC h (5.1)Tj T* (5 \346g/m3 TWA \(listed under )Tj f 0 -1.201 TD )Tj 9.226 386.514 l W* n 9.226 412.655 l ( Chromium trioxide: No OSHA Vacated PELs are listed for this chemical. 306.769 618.319 l h W* n /T1_0 1 Tf h W* n h Q f h h h 602.774 443.793 l W* n 600.467 388.82 l 602.774 407.621 l 9.226 253.789 l 10.764 383.018 l W* n 0 18 612 756 re 9.226 53.471 l /TT1 1 Tf 1333-82-0 Chromium trioxide >98 215-607-8 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: dark red to purple solid. 604.312 322.179 l f BT Immediately flush skin with plenty of wate\ r for at least 15 minutes while )Tj (California No Significant Risk Level: None of the chemicals in this prod\ uct are listed. 9.226 494.862 l 156.46 618.319 l (oxygen.. )Tj 602.774 133.047 l /Artifact <>BDC h 11.533 684.507 l 7.688 226.111 m ( No information )Tj 363.873 93.836 l 305.231 542.588 l 7.688 322.179 m EMC f 157.229 631.005 l 122.292 443.793 254.349 11.917 re 0 0 0 rg 0000066330 00000 n f /TT0 1 Tf 603.543 66.157 l ( )Tj /TT0 1 Tf 0 -1.201 TD 602.774 141.56 l 0 -1.201 TD 603.543 93.067 m 157.229 631.005 m 600.467 117.726 l (The information above is believed to be accurate and represents the best\ information currently available to us. 7.688 767.849 m 377.41 443.024 l 10.764 493.324 m h 122.666 66.157 l 9.226 677.857 l h 600.467 704.023 l 602.774 739.538 l :��i�l�������J���ɖ����"�������5/B�aۅ�ifb~�A8蟵i��������u!�r�{���Q[�u�G������������]0�{�޾ ?�������>�]����w ( None of the chemicals in this product are listed as Hazardous Subst\ ances under the CWA. /TT1 1 Tf h 0 -1.201 TD May cause )Tj 13.4548 0 0 13.4548 184.2679 146.6595 Tm 602.774 491.077 l \ )Tj 0 -1.2 TD 121.897 93.836 l h 10.764 472.603 l 0 -1.2 TD 0000001082 00000 n 0 -1.201 TD The related chromium(III) derivatives are not particularly dangerous; thus, reductants are used to destroy chromium(VI) samples. 5.3819 0 0 5.3819 27.4577 476.7533 Tm 0 0 0 rg 7.688 676.32 m 604.312 131.509 l f 454.771 541.819 m 604.312 767.849 l Do not breathe dust, mist, or vapor. 602.774 430.338 l Q (Percent)Tj Q 0 -1.201 TD 0 -1.2 TD Strong oxidiz\ er. EMC (2.7 \(Water=1\) )Tj 9.226 618.319 147.234 11.917 re h 604.312 255.327 m (other symptoms are experienced. f f /TT1 1 Tf f f May cause allergic skin reaction. f 10.764 679.395 m 602.774 227.648 l 0 -1.199 TD 7.688 322.179 l 0000002078 00000 n 8.457 52.702 m 305.231 630.236 l h (under Chromium \(VI\) )Tj 362.335 66.926 l T* h 600.467 701.691 l 7.688 274.942 m 121.524 429.569 l T* (Clean Water Act:)Tj 9.226 443.793 l 8.457 79.612 m 0.457 0.449 0.431 rg 362.335 119.207 l 9.226 141.56 l -42.948 -1.555 Td 306 541.819 m Inhal\ ation may be fatal as a result of spasm, )Tj 122.666 106.521 m h q Q /TT1 1 Tf W* n FIRST-AID MEASURES Eyes In case of eye contact, rinse with plenty of water and seek medical attention immediately. 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm 9.9358 0 0 9.9358 212.3056 223.0145 Tm They can spread along the ground and )Tj 0 18 612 756 re 604.312 165.687 m W* n f h 27.798 0 Td 601.236 515.68 l 10.764 741.075 m W* n W* n EMC ( S 60 This material and its container must be disposed of as hazardo\ u )Tj 10.764 139.547 m 602.774 381.48 l h 8.457 541.819 l 0 -1.2 TD ET ( CAS# 1333-82-0 can be found on the following state right to know li\ sts: New Jersey, Pennsylvania, Minnesota, )Tj 602.774 138.009 l /Artifact <>BDC 484.526 429.569 m reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and. 0 -1.201 TD 363.104 106.521 l f ( 703-527-3887 )Tj 11.533 410.348 l ( R 46 May cause heritable genetic damage. 7.688 428.8 m f <> 601.236 515.68 m Causes )Tj 602.774 119.207 l endstream endobj 32 0 obj<> endobj 33 0 obj<>stream T* 10.764 702.46 m It is usually produced by an industrial process. (Safety Phrases:)Tj (hazard. ( )Tj 483.757 430.338 l f 0000000004 65535 f (General Information:)Tj ( )Tj 11.533 473.371 l f ( Wear a chemical apron. /TT0 1 Tf ( A1 - Confirmed Human Carcinogen \(listed as 'Chromium \(VI\) compounds-\ water soluble'\). 0.801 0.801 0.801 rg T* ( )Tj /TT1 1 Tf Causes burns by all exposure routes. 363.104 93.067 l 11.533 405.314 l h May cause cyanosis \(bluish discoloration of skin due to \ deficient oxygenation of the blood\). ( )Tj T* 0 0 0 rg Q 13.4548 0 0 13.4548 181.9201 255.9136 Tm /TT0 1 Tf 10.764 470.259 m f Q q 157.997 618.319 l ( AC196610000, AC196610010, AC196610250, AC196612500, AC214100000, AC2141\ 00010, )Tj 3 99.99 g/mol 4 generators must ) Tj 0 -1.2 TD ( skin: Tj... When wet and which dissolves in water concomitant with hydrolysis ( HNOC ) hazards... Known to cause cancer act with thermal decomposition products, liver, skin and eyes suitability of the hands.! 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